Oxidation and Reduction of Ir(100) Studied by High-Energy Surface X-ray Diffraction

نویسندگان

چکیده

The oxidation and reduction of an Ir(100) surface using 2.5, 5, 10 mbar O2 partial pressure a sample temperature 775 K have been studied by high-energy X-ray diffraction (HESXRD) which allowed to record large volumes reciprocal space in short time periods. complex 3D patterns could be disentangled stepwise procedure. For the 2.5 experiment measurements indicate formation Ir(100)-O c(2 × 2) oxygen superstructure along with onset epitaxial IrO2(110) bulk oxide formation. 5 pressures additional IrO2 epitaxies (100) (101) orientations as well polycrystalline was observed. Upon CO reduction, we found islands reduced into metallic Ir(111) (221) oriented islands.

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ژورنال

عنوان ژورنال: Journal of Physical Chemistry C

سال: 2022

ISSN: ['1932-7455', '1932-7447']

DOI: https://doi.org/10.1021/acs.jpcc.1c10250